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Energetics and local order in In-based liquid alloys


 
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1. Title Title of document Energetics and local order in In-based liquid alloys
 
2. Creator Author's name, affiliation, country RP Koirala; University Department of Physics, T.M. Bhagalpur University, Bhagalpur, India; Department of Physics, M.M.A.M. Campus, Biratnagar, Tribhuvan University; Nepal
 
2. Creator Author's name, affiliation, country BP Singh; University Department of Physics, T.M. Bhagalpur University, Bhagalpur; India
 
2. Creator Author's name, affiliation, country IS Jha; Department of Physics, M.M.A.M. Campus, Biratnagar, Tribhuvan University; Nepal
 
2. Creator Author's name, affiliation, country D Adhikari; Department of Physics, M.M.A.M. Campus, Biratnagar, Tribhuvan University; Nepal
 
3. Subject Discipline(s) Physics; Chemistry; Material Science, Engineering, Condensed matter Physics
 
3. Subject Keyword(s) Liquid alloys; Self association model; Order energy; Segregation
 
4. Description Abstract

A comparative study has been carried out to understand the concentration dependence of thermodynamic properties such as, free energy of mixing, heat of mixing, entropy of mixing, activity  and microscopic properties, such as concentration fluctuation in long wavelength limit  and Warren-Cowley short range order parameter  of  In-based three liquid alloys (In-Pb , In-Tl and In-Zn) on the basis of self-association model. The analysis reveals that self-association model successfully explains the observed properties of the liquid alloys.  Positive deviation of the thermodynamic properties of the alloys from the Raoultian solution behaviour indicates that the alloys are weakly segregating in nature. The comparative assessment of the interaction energy and the microscopic properties suggests that the degree of segregation is greatest in In-Zn alloy and comparable in In-Pb and In-Tl alloys.

BIBECHANA 13 (2016) 60-71

 
5. Publisher Organizing agency, location Birat Campus, Biratnagar, Nepal
 
6. Contributor Sponsor(s)
 
7. Date (YYYY-MM-DD) 2015-12-03
 
8. Type Status & genre Peer-Reviewed Article
 
8. Type Type
 
9. Format File format PDF
 
10. Identifier Uniform Resource Identifier https://www.nepjol.info/index.php/BIBECHANA/article/view/13359
 
10. Identifier Digital Object Identifier http://dx.doi.org/10.3126/bibechana.v13i0.13359
 
11. Source Title; vol., no. (year) BIBECHANA; Vol 13 (2016)
 
12. Language English=en en
 
13. Relation Supp. Files
 
14. Coverage Geo-spatial location, chronological period, research sample (gender, age, etc.) Global
 
15. Rights Copyright and permissions Copyright (c) 2015 BIBECHANA